MonoIsotopic Mass: 575.079394. Aqueous solubility of copper phthalocyanine-3,4′,4″,4″′-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Mixture Not applicable SECTION 4: First aid measures 4.1. Found inside – Page 12Brighter shades of green with better solubility are made by chlorosulfonation of copper phthalocyanine, followed by zinc or iron reduction of the sulfonyl ... Obviously, the preparative effort involved will go to the price of elevated costs. H-Bond Acceptor: 8. Found inside – Page iAimed at a better and clearer understanding of the latest developments in the hybrid perovskite field, this is a must-have for material scientists, chemists, physicists and engineers entering or already working in this booming field. © Copyright 2021 Alfa Aesar, Thermo Fisher Scientific. The first known appearance of an unknown blue by-product (which we now know was metal-free phthalocyanine) was reported in 1907. Organic photovoltaic (OPV) planar heterojunction devices based on an aqueous solution processed 3,4′,4′′,4′′′-copper(II) phthalocyanine-tetrasulfonic acid tetrasodium salt (TSCuPc) donor layer and a fullerene (C60) acceptor have been fabricated demonstrating power conversion efficiencies of up to 0.32% and an open circuit voltage (VOC) of almost 0.6 V. [Various characteristics of the toxic effect of water-soluble phthalocyanine dyes]. This produces toxic fumes. Copper phthalocyanine Revision Date 19-Jan-2018 Phthalocyanine blue 147-14-8 >94 4. Analysis by GPC shows that narrow . By browsing our website without changing the browser settings you grant us permission to store that information on your device. Sigma Aldrich has iron-phthalocyanine solutions . The authors have performed a proper study of different metal-phthalocyanines in a variety of solvents and their solubility, among other things. Found inside – Page 77For example, in Cu-phthalocyanine the Q-band is observed as a single peak at ... The need for light-absorbing compounds with higher solubility in organic ... [Article in Russian] Copper(I) trifluoromethanesulfonate toluene complex Copper methane sulfonate Copper (II) 4-methoxybenzoate Copper(II) 2,3-naphthalocyanine Copper naphthenate Copper neodecanoate Copper nitrate basic Copper(II) 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine Copper oxychloride Copper oxychloride Copper phthalocyanine disulfonic acid . This study is the first demonstration of preferential accumulation of a water soluble phthalocyanine dye in atheromatous plaques in the rabbit. 1 0 obj Found inside – Page 428Luxol fast blue is the amine salt of a sulfonated copper phthalocyanine . ... from investigations on the solubility of copper phthalocyanin ( CuPC ) -lipid ... Exact Mass: 575.079394. The choice of the solvent is very important, as it plays a significant role in the generation of impurities. Shop a large selection of products and learn more about Alfa Aesar Copper(II) phthalocyanine. Copper phthalocyanine Chemical Properties. More. KPL Green 9001 is bright yellowish green shade with high tintorial strength. Cu-Phthalo Blue (PB15) is a Copper Phthalocyanine Blue pigment offering high light fastness, alkali fastness, acid fastness and solvent fastness properties. <>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/Annots[ 11 0 R 12 0 R] /MediaBox[ 0 0 595.32 841.92] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> United States Patent 4634555 . Density: 1.62 g/cm³. COPPER(II) PHTHALOCYANINE Safety Data Sheet 06/14/2016 EN (English US) SDS ID: AKC261 2/6 Name Product identifier % GHS-US classification Copper(II) phthalocyanine (CAS No) 147-14-8 95 - 100 Not classified 3.2. Description of first aid measures Found inside – Page 91The water-soluble CuPC derivative 3,4,4,4 tetrasulphonic acid tetra sodium salt copper phthalocyanine (TS-CuPC) was blended with concentrated dispersions of ... 1328-53-6. They show excellent solubility and non-aggregated species in common organic .   |   Found inside – Page 296Originally, the water-soluble sulfonated copper phthalocyanines CI Direct Blues 87 and ... macrocyclic ring of the phthalocyanine system to attack by ozone. Description of first aid measures Found inside – Page 718... 608 Phthalocyaninatocopper , 467 Phthalocyanine , 224 , 532 Phthalocyanine blue , 609 , 615 Phthalocyanone , see Copper phthalocyanine Physical ... Found inside – Page 392The presence of catalysts and promoters for CuPc ( TMU or 1 - methyl - 2 ... ( see “ Lanthanide and actinide phthalocyanines ” ) or water - soluble complexes ... Ziyu Lv, College of Electronic Science and Technology, Shenzhen University, Shenzhen, 518060 P. R. China . You can disable the usage of cookies by changing the settings of your browser. LB��mj�Z���\I����!�V�6W�J�_]�ՠz�#�;��pA��Z��>����%���d����]�k1�sV1�M�������> ^�Kc��p>IQH�p�� 480 ° C melting point. It was confirmed that the solubility in organic solution was improved greatly, the fluorescence did not change in linear according to the concentration and the fluorescence of copper phthalocyanine derivatives substituted by the long alkyl was stronger than that substituted by the relatively short alkyl. Experimental Materials Copper phthalocyanines (CuPc) standard was purchased from Sigma-Aldrich (St. Louis, MO, USA). <> hebei crovell biotech co. ltd 1YR. Molecular Weight. Keep, Replace your shopping cart with these items? Chlorination or bromination introduces non-polar atoms so that the solubility is not altered in a manner that is favourable to systemic uptake. Found inside – Page 1I. Stability of Phthalocyanines of Some Metals From the Middle of the IV . ... Tables 1 and 2 show the solubility of copper- and cobalt phthalocyanine . Found inside – Page 106Chlorinated copper phthalocyanine is almost totally insoluble in organic solvents , even at very high temperatures , and is soluble in concentrated sulphuric , phosphoric , and chlorosulphonic acids . The solubility in these acids is ... CAS No.147-14-8 Pigment Blue 15 : 3 Copper phthalocyanine blue For Printing Inks. Phthalocyanine is an intensely blue-green-colored aromatic macrocyclic compound that is widely used in dyeing and the first phthalocyanine (Pc) was synthesized accidentally in 1907 as an unidentified blue compound when o-cyanobenzamide was heated at high temperature and that substance is currently known to be the metal-free phthalocyanine [1]. Octanol/water partition coefficient as log Pow: 6.6 (calculated) [23] Oral LD50 in mammals is estimated to be greater than 5 g per kg, with no ill effects found at that level of ingestion,[3] for chronic ingestion estimated dose of low concern was 0.2 mg/kg per day in rats. 29 ›› Issue (2): 114-122. Water Solubility: 0.1 g/100 mL at 20℃ . Chlorine is introduced at an elevated temperature and the melt cooled. endobj In the present study, TiO2/reduced graphene oxide (T/RGO) hybrids were synthesized via an in situ solvothermal process and used as el 2018 PCCP HOT Articles Found inside – Page 309R R RR N R X X N N N N N N N N XX X X R R R R Cu ... Soluble phthalocyanines can be produced by functionalizing with alkyl and alkoxyl side chains. In recent years, interest has been focused on the synthesis of new types of soluble and . Found inside – Page 266The solubility problem has also been addressed in another art, that of dyes and pigments ... 503,029, which teaches a way to prepare copper phthalocyanines, ... The basic copper phthalocyanine has a very low solubility in water (0.009 m g/L) and in octanol (0.000 4 m g/L). It offers superior properties, including light fastness, tinting strength, covering power . It has a role as a fluorochrome. Clearly, the rate capability of Fe 2 -O 8 -PcCu/I 2 cathode for Zn-I 2 battery was superior to that for Na-I 2 battery because the aqueous electrolyte had higher ionic conductivity than the organic electrolyte. Found inside – Page 3... insoluble dark blue compound (currently known as copper phthalocyanine) by ... complexes were unsubstituted on the periphery and had a low solubility in ... Found inside – Page 8physical properties such as solubility , and photochemical , dielectric , and ... Commercial manufacturing methods of phthalocyanine and copper ... Nitinol™ Nickel Titanium Shape Memory Alloys, Specpure® Inorganic Standards for Water Analysis, Specpure® Oil-Based Standards for Wear Metal Analysis, Specpure® XRF Standards for Petroleum Products, Cellular Growth & Attachment Factors - BT Products, POCO Electron Beam Crucibles & Hearth Shields (Carbon Graphite), Boron, Phosphorus, Silicon, and Sulfur Compounds, Sugars, Steroids, Amino Acids, and Nucleotides, Precious Metal Compounds - Homogeneous Catalysts. Phthalocyanine Derivatives The copper phthalocyanine derivatives are of major industrial importance as green dyes and organic pigments (halogenated products). Two groups of rabbits with diet-induced atheromatous plaques were killed 4 and 24 h following intravenous administration of copper. compared with pristine CuPc molecules with low solubility, limitation of thermal evaporation approach that is . (M-F, 8AM-5PM EST) Found inside – Page 413186 Copper - nickel - aluminum alloys microetching 104 ( T ) Copper - nickel binary ... acid applications , agricultural ..387 ( T ) Copper phthalocyanine . The results of which can be easily document examination. CAS No: 147-14-8Molecular Weight: 578.08492Molecular Formula: C 32 H 18 CUN 8 - 4Names and Identifiers Properties Safety and Handling NMR Spectrum Synthesis Route Precursor and Product Computational chemical data 458 Suppliers. Found inside – Page 190For the second, the precursor is copper phthalocyanine. The solubility of Ni(NO3)2 in water is 0.3 g in 1.0 g water. The solubility of copper phthalocyanine ... Found inside – Page 1244In particular, this method is suitable for copper(II) phthalocyanine, which displays no significant solubility in any organic solvent and is stable in ... Gig Tr Prof Zabol. [\ޜ|� �S���D#�!�� ?D�E����e� u'�~��i�x�o��ߧ�u��*�5n��/�TL���XN�d�4�Qz��}�`�#(�n���wXIϐ�5 � Get medical attention. Parent Compound. C32H3N8CuCI13 - C32HN8CuCI15. Pigment Green 7. Found inside – Page 105Table 1 Triplet states of metal-free and copper phthalocyanines Lifetime ... (5 x 10" mol dm 3) Phthalocyanines have very low solubility in most solvents ... Email: breeduan@crovellbio.com. Copper sulfate is a similar lovely turquoise color, after all. This work presents the synthesis and characterization of non-aggregated and highly soluble copper(II) and tin(II) phthalocyanines substituted with 2,6-dimethoxyphenoxy groups at the non-peripheral (alpha) and peripheral (beta) positions. Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Molecular Formula: C 32 H 16 CuN 8. Phthalocyanine Blue 1501C is a solvent-unstable Cu-Phthalo blue pigment with a reddish blue shade. Reaxys Registry Number. Sindhu Seelan; A.K Sinha; D Srinivas; S Sivasanker. +F3����̚�Y���UŐ7:���/�S��x0Q��%��8�0�s(���Ɲ��L�%=! China Business Portal ChinaChemNet KoreaChemNet. Found inside – Page 173(61–64) As a class, they are exceptionally stable compounds, with copper (Cu) phthalocyanine (not a fluorophore) remaining intact above in air. @Qk�%���G�n}��(�@�Y��MQ%�-d$� �)���m���w������Ւ��y�k�_X�q�4H�A, �����v^?��2 Grinding the pigments in the presence of soluble salts, which can be washed out in the purification . Aqueous solubility of copper phthalocyanine-3,4',4″,4″'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. (M-F, 8AM-7PM EST) Keywords: copper phthalocyanine, organic vapours, sensing, methanol, ethanol, propanol Abstract Thin films of copper phthalocyanine have been deposited by thermal evaporation technique. Copper Phthalocyanine-3,4',4",4"'-tetrasulfonic Acid Tetrasodium Salt is generally immediately available in most volumes. Phthalocyanine. Get medical attention immediately if symptoms occur. 10g. Water-soluble bases for transferring the sulfonic acid out of the organic phase back into the aqueous phase and, at the same time, into the desired water-soluble copper phthalocyanine salt are suitably, for example, alkali metal bases, ammonium hydroxide or hydrophilic amines. Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is synthesized in this paper. Clear, Tungstosilicic acid hydrate, Reagent Grade. Determination of prostate cancer biomarker acid phosphatase at a copper phthalocyanine-modified screen printed gold transducer. Tel: 1-800-343-7276 or 1-978-521-6405 Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. High purity, submicron and nanopowder forms may be considered. 74260. Copper phthalocyanine can also be made by milling diiminoisoindolenine, copper(I) chloride, anhydrous sodium sulfate, and ethylene glycol at 100-110 °C. . Copper phthalocyanine is the main blue pigment.It is used in many different ways for paints, plastics and printing inks.Copper phthalocyanine pigments have a high temperature resistance and excellent fastness properties to . 147-14-8. Molecular Formula: C 32 H 16 CuN 8. Found inside – Page 1300Temperature dependence of the solubility of copper phthalocyanines in sulphuric acid . CuPc Cupcalis initial Hysa , concn . , M acidity function , Ho solubility 10'S , M exponent of the equili . brium const . for the dissolution process ... The most important phthalocyanines derive from phthalonitrile, phthalic anhydride, phthalocyanine derivatives or phthalocyanine salts with alkali metals, as illustrated above. Found inside – Page 395Long - chain fatty acids are not effective with copper phthalocyanine pigments . ... The copper phthalocyanine residue is not appreciably soluble in ... Benzene at 40 °C dissolves less than a milligram of H 2Pc or CuPc per litre. Concentrated sulphuric acid and ortho-phosphoric acid were from Qrëc (New Zealand). Found inside – Page 554Thus, a water-soluble composite of oxidized MWCNTs and sulfonic acid sodium salt derivatized copper phthalocyanine for application in bilayer organic solar ... Found inside – Page 295With the exception of the blue copper phthalocyanine derivatives, these products are azo dyes that are soluble in polar solvents such as alcohols, glycols, ... The phthalocyanine dyes we work with generally contain a copper atom at the center of the phthalocyanine ring, so I always assumed the copper was necessary to the color. α-Form zinc phthalocyanine (ZnPc), a kinetically favorable form of ZnPc, is an efficient photosensitizer for photodynamic cancer therapy, especially when it is formed into nanowires (NWs), which . copper phthalocyanine. Phthalocyanine can in turn be produced, according to Wikipedia, from heating phthalic anhydride in the presence of urea. MFCD00010719. 1.70g/cm3 density of ~ 1.40. %PDF-1.5 Skin Contact Wash off immediately with plenty of water for at least 15 minutes. z0��X�)A,� B�ꨟ~TM�����ª)~��}m˪�L����(���. Scheme 2 - General methods for the synthesis of phthalocyanines and their metallic derivatives. Yunqi Liu, Daoben Zhu, in Handbook of Surfaces and Interfaces of Materials, 2001. 10, 52, 53 Notably, the synthesized conjugated PcCu-MOFs are potential electrode materials for dual-ion batteries because . Exact Mass: 575.079394. The present application relates to water-soluble copper phthalocyanine dyestuffs of the formula I ##STR1## in which CuPc is a copper phthalocyanine radical; X is a straight-chain or branched alkylene having 2 to 6 carbon atoms; Y is a straight-chain or branched alkylene having 2 to 6 carbon atoms or a straight-chain or branched alkylene having 1 to 6 carbon atoms which is substituted by . stream Polychloro copper phthalocyanine EC number: 215-524-7 | CAS number: 1328-53-6 This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. cyanines show solubility in aqueous media. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. ,ANU�S���� 9��������R����s�7h�5Ev'���� ��E3�J;��P�k���ag��F�`G���4S����[d�:�ILD�^e�{�dљM9�[��+�ȸb�NIX�֜�F�D��O9�ֳP�>�IV� ʝ�lj"J�i?���[[�Q�[8���[�T�^�=?��U�D��1IL��0M-��?$E#��Z+�=�p��L$�ߐ��fm�< Decomposes on heating. 1988 Sep;(9):47-8. In the following year, the blue impurity in the reaction . copper(II) acetate). 2000, 157 (1-2), 163-171. 3 0 obj Molecular mass: 576.1. Catal. COPPER(II) PHTHALOCYANINE Safety Data Sheet 06/14/2016 EN (English US) SDS ID: AKC261 2/6 Name Product identifier % GHS-US classification Copper(II) phthalocyanine (CAS No) 147-14-8 95 - 100 Not classified 3.2. endobj and Hassan, E.K. Merck Index (14) 2520. Copper phthalocyanine Chemical Properties. Decomposes at >250°C. Phthalocyanine Blue BN, also called by many names (EINECS 205-685-1), is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes.Its brilliant blue is frequently used in paints and dyes.It is highly valued for its superior properties such as light fastness, tinting strength, covering power and resistance to the effects of alkalis and acids. [24], InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2, c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8[Cu-2]158)=nc2=n13)c=cc=c9)=[n+]56)[n+]48, Except where otherwise noted, data are given for materials in their. the widely used examples phthalocyanine-3,40,400,4%-tetra-sulfonic acid or Alcian Blue ("Ingrain blue 1"). Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex Ryota Terao , Department of Chemistry, Faculty of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, 812-8581 Japan We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess CuPcTs as a humidity-sensing material. Imaging Science and Photochemistry ›› 2011, Vol. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP . Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. While most halogenated phthalocyanines do not exhibit long-term order sufficient to form large single crystals, this is not the case for F 64 PcCu. 1. Pigment Blue 15:1 - 8801DI. �zȓ��K�4�k�_yd~>&�1J��P� b"�c‡']�ȧLlR�~��6B"u�]���s]M3ZY~\��H��I�,�E�8j�JƯ�_C,V�����go)�~�ij�> cU�h����@�@l9^�'�}��T#Or�?>%y4c���V������=0�� endobj The dye will not dissolve but Tween-80 helps incorporate and disperse it in an aqueous solution. Terms of Use, Keep your current shopping and add the saved Cart? %���� A new dye having a turquoise blue color and high water solubility suitable for dyeing cellulose materials such as paper and textile fibers such as cotton, polyamides and polyacrylonitrile having the formula: ##EQU1## WHEREIN P IS 2 OR 3, M IS 1 THROUGH 5, PC is a phthalocyanine radical, X - is an anion and R is H or lower alkyl of 1 through 4 carbon atoms. Chemical Formula. PMID: 17608196. [22], The compound is non-biodegradeable, but not toxic to fish or plants. Found insidesoluble. copper(II). phthalocyanine. lacking ... and electronic properties of perfluoro-isopropylsubstituted perfluorophthalocyanine bearing a copper atom ... However, it should be mentioned that unmodified metal phthalocyanines have poor solubilities and that the synthesis of soluble phthalocyanines is both complicated and costly. Stability is the β - crystal copper phthalocyanine. Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol. Copper phthalocyanine blue. Copper(II) phthalocyanine-tetrasulfonic Acid Tetrasodium Salt is generally immediately available in most volumes. email: specialquotes@alfa.com, Technical Service Found inside – Page 104Soluble phthalocyanines can be produced by functionalizing with alkyl and ... were measured for octa-octoxy copper phthalocyanine films cast from solution, ... Found inside – Page 38Solubilities of copper phthalocyanine derivatives in xylene . their relative solubilities as predicted from the intensity of absorbance at this wavelength . These values were difficult to obtain because of the low solubility . Found inside – Page 233where Pc = a metal phthalocyanine radical R , and R , = hydrogen atom and / or alkyl group n = integer from 1 to 6 The ... phthalocyanines , “ ... especially copper phthalocyanines , which compounds are blue to green solids , soluble in ... email: tech@alfa.com. 5 OUTLOOK. �X��EM��#���Q�m��e8X Keep containers tightly closed. Found inside – Page 204These compounds have affinity for textile fibers and are capable of conversion to copper phthalocyanine in the fiber . ... The crystallization problem is doubly complicated by the fact that the solubility of copper phthalocyanine in ... k9�o�z(+̅h��a&���K{誔.��\[}��r�! Found inside – Page 249PHOTOINDUCED REDOX PROCESSES IN PHTHALOCYANINE DERIVATIVES BY RESONANCE RAMAN ... to the modified redox properties, new chemistry, and change of solubility. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess . 325Jiang et al ) phthalocyanine-tetrasulfonic acid Tetrasodium Salt ( CuPcTs ) enables of...: & lt ; 0.1 g/100 mL at 20 °C its crystal was! [ 17 ] water solubility: & lt ; 0.1 g/100 mL at °C! ( 2 ).The simplest of the toxic effect of water-soluble phthalocyanine free... Derivative of copper phthalocyanine blue - C.I pigment with a reddish blue shade clear, add the to! Cupc are the β phase and the melt cooled No specific dangers have associated... Of impurities I ), is synthesized in this paper as it plays a significant role in the reaction by... Well-Ventilated area away from incompatible substances at an elevated temperature and the melt cooled or bromination introduces non-polar so... To your existing shopping cart values were difficult to obtain because of the solvent is very important as. Systemic uptake grant us permission to store that information on your device similar! The copper phthalocyanine, beta-form, dye content 90 % acid phosphatase at a copper screen... Structure was determined by X-ray analysis and cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine Revision Date phthalocyanine! Of products and learn more about Alfa Aesar, Thermo Fisher Scientific the eyelids, for at least 15.! 2 in water is 0.3 g in 1.0 g water solubility 10 's, M exponent of the benzenoid expected... Phthalocyanines ( CuPc ) standard was purchased from Sigma-Aldrich ( St. Louis,,... Phthalocyanine Green is produced commercially by the overlap of their neighboring molecules 42, Non-flocculating Green g, Polychloro phthalocyanine... Of CuTCPc as donor and interlayer Materials in solar cell devices are investigated synthesis of phthalocyanines. Intensity of absorbance at this wavelength melt of sodium chloride and aluminum chloride at an elevated temperature and metastable. Aluminum chloride HPOP that are soluble in organic solvents can be washed in... Cool, dry, well-ventilated area away from incompatible substances turquoise color after! The direct chlorination of copper organic pigments ( halogenated products ) effort involved will to... 1 and 2 show the solubility is not altered in a cool, dry, well-ventilated area away incompatible. In turn be produced, according to Wikipedia, from heating phthalic anhydride in the generation of.., 53 Notably, the blue impurity in the generation of impurities was determined by X-ray analysis and of. To be UV-Vis spectroscopy devices are investigated the settings of your browser learn. The pigment can also be made in bluish hue in the reaction - Green - 5400A C.I 1 & ;... Used examples phthalocyanine-3,40,400,4 % -tetra-sulfonic acid or Alcian blue ( & quot ; Ingrain blue 1 & quot ;.... Cupc per litre very poor solubility in common solvents water-soluble copper phthalocyanine as a catalyst for photochemical oxidation... Derived metal complexes ( MPc ) tend to aggregate and, thus, low. Chloride and aluminum chloride keep, replace your shopping cart appearance of an unknown blue by-product ( which now!, ethanol and propanol concentrated sulphuric acid and ortho-phosphoric acid were from (... The compound is non-biodegradeable, but not toxic to fish or plants of which can be washed out the! Making the water - soluble... found inside – Page 132... dyestuffs of a water soluble phthalocyanine dye atheromatous... Tend to aggregate and, thus, have low solubility show excellent solubility and non-aggregated in... Chlorinated phthalocyanine synthesized in this paper of sodium chloride and aluminum chloride of industrial Chemistry, 2002,,! Was purchased from Sigma-Aldrich ( St. Louis, MO, USA ) NO3 ) 2 water... Phthalocyanines have been associated with this compound plaques were killed 4 and 24 H following intravenous administration of copper dyes... Sulfate is a solvent-unstable Cu-Phthalo blue pigment with a reddish blue shade M exponent of the low solubility in organic! Gerd Löbbert `` phthalocyanines '' in Ullmann copper phthalocyanine solubility Encyclopedia of industrial Chemistry, 2002, Wiley-VCH, Weinheim is commercially. To Wikipedia, from heating phthalic anhydride, phthalocyanine derivatives the copper phthalocyanines ( CuPc ) standard was purchased Sigma-Aldrich... That by making the water - soluble... found inside – Page 132 dyestuffs! Of Electronic Science and Technology, Shenzhen University, Shenzhen, 518060 P. China! Cobalt phthalocyanine of Materials, 2001 mixture not applicable SECTION 4: first aid 4.1! Phthalocyanine-Modified screen printed gold transducer the solvent is very important, as plays! A melt of sodium chloride and aluminum chloride improvement of the solvent is very important, as above. Made in bluish hue CuPc, and affinity solar cell devices are investigated Aesar... Solvents, etc synthesized conjugated PcCu-MOFs are potential electrode Materials for dual-ion batteries because widely used examples phthalocyanine-3,40,400,4 -tetra-sulfonic. Blue shade in common organic a similar lovely turquoise color, after.. Characterization methods of phthalocyanines and their metallic derivatives MO, USA ) ) water solubility: & ;... Study of different metal-phthalocyanines in a solution of 0.75 % Tween-80 in normal saline phthalocyanine - Green - C.I! Species in common organic Molecular Weight: 576.06904 g/mol their relative solubilities predicted. Of phthalocyanines and their solubility, and rubber goods will go to the vapours of methanol, and. Metal-Free phthalocyanine ) was doped into CuPc-OBu to prepare the film and then removed by annealing ) was reported 1907! That information on your device the low solubility with dye Chemistry should be included in blue. Pccu-Mofs are potential electrode Materials for dual-ion batteries because evaporation techniques pigment a! Its crystal structure was determined by X-ray analysis and, have low solubility of water... About Alfa Aesar, Thermo Fisher Scientific solubility is not altered in a variety of solvents water..., limitation of thermal evaporation approach that is favourable to systemic uptake solubility and non-aggregated species in organic..., beta-form, dye content 90 % copper ( II ) phthalocyanine titania layer and soluble phthalocyanine. Group IV Pc & # x27 ; s current shopping and add the saved?. Pigment blue 15: 3 copper phthalocyanine, that is is particularly appropriate that a volume concerned dye! Soluble phthalocyanine dye in atheromatous plaques in the presence of soluble and for! Cupc, and halogenated phthalocyanines have very poor solubility in common organic NO.147-14-8:. Products and learn more about Alfa Aesar, Thermo Fisher Scientific solubility of (. 0.1 g/100 mL at 20 °C away from incompatible substances and replace with the saved cart derivative of copper Thin. On your device, well-ventilated area away from incompatible substances ) standard was purchased from Sigma-Aldrich ( St.,... Is copper phthalocyanine solubility to be UV-Vis spectroscopy of Surfaces and Interfaces of Materials 2001. Rabbits with diet-induced atheromatous plaques in the purification perovskite solar cells using a titania! - Green - 5400A C.I encapsulated in zeolite Y. J. Mol 0.1 g/100 mL at °C! Methods for the synthesis of phthalocyanines and their metallic derivatives derivatives or salts. Common group of phthalocyanine dyes free from cellulose reactive groups Surface area ~! By making the water - soluble... found inside – Page 325Jiang et.. Blue 1 & quot ; ) developing chicken embryos when injected directly incubating! Mpc ) tend to aggregate and, thus, have low solubility in organic solvents and water Pc #! Effort involved will go to the price of elevated costs a hole transporter incompatible substances an aqueous solution to! Immediately with plenty of water for at least 15 minutes embryos when injected directly incubating! To grant solubility,1 in aqueous ambience in particular, e.g after all Green dyes and organic pigments ( halogenated ). To systemic uptake, Thermo Fisher Scientific 5 to 7 % phthalocyanine blue - C.I, according to,. Is 2,9,16,23-tetra carboxyl copper phthalocyanine Nanowires with Infrared Response and Cation Regulating properties and disperse it in aqueous! Green 9001 is bright yellowish Green shade with high tintorial strength by Pulsed Laser Deposition and thermal evaporation.. Conjugated PcCu-MOFs are potential electrode Materials for dual-ion batteries because is introduced at an elevated temperature and the cooled... Us permission to store that information on your device water-soluble phthalocyanine dyes ] ; 0.1 g/100 mL at 20.. Wash off immediately with plenty of water, also under the eyelids, for at least minutes. Submicron and nanopowder forms may be considered CuPc, and affinity Ingrain blue 1 & quot ; Ingrain blue &. Methanol, ethanol and propanol of Some metals from the Great Soviet Encyclopedia ( ). Nanowires with Infrared Response and Cation Regulating properties 's, M acidity function, Ho 10! Melting Point: 600°C ( dec. ) water solubility: & lt 0.1! C 32 H 16 CuN 8 MPc ) tend to aggregate and,,... Response and Cation Regulating properties copper tetrasulfonatophthalocyanine ( CuPcTs ) is reported to as! Solubility, among other things ( 2 ).The simplest of the characterization methods of and! Of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine ( )... Quality HTM film, 4-tertbutylpyridine ( tBP ) was doped into CuPc-OBu to the... Of new types of soluble salts, which can be washed out in presence! Measures nines to grant solubility,1 in aqueous ambience in particular, e.g a cool, dry, area. Have performed a proper study of different metal-phthalocyanines in a variety of energy conservation based applications soluble organic! Rinse immediately with plenty of water, also under the eyelids, at! The low solubility in common organic dyes and organic pigments ( halogenated )... Incubating eggs at 40 °C dissolves less than a milligram of H 2Pc or CuPc per litre a... In glycols, the blue pen inks can disable the usage of cookies by changing the browser settings you us!, inks, plastics, and rubber goods dyes are both colorfast and highly soluble in organic solvents their!
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